Electroless deposited (ELD) cobalt with palladium as a catalyst, and an underlying self-assembled monolayer (SAM) was investigated for potential use in advanced complementary metal oxide semiconductor (CMOS) applications using both hard (HAXPES) and soft (XPS) x-ray photoelectron spectroscopy. HAXPES spectra established the uniformity of the deposited Co film and the nature of the buried Co-Si interface ~20nm below the surface. The Pd is seen to diffuse through the Co following thermal annealing. While the deposited Co film is predominantly metallic, Co-silicide forms at the Co-Si interface upon deposition and decomposes with thermal anneal up to 500°C.
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Publication Type = Conference or Workshop Item
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Dublin City University ->
Status = Published
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Dublin City University ->
Subject = Physical Sciences: Physics
Ireland ->
Dublin City University ->
Subject = Physical Sciences
Ireland ->
Dublin City University ->
DCU Faculties and Centres = DCU Faculties and Schools: Faculty of Science and Health: School of Physical Sciences
Justin Bogan,
Greg Hughes,
Venkateswaran Selvaraju,
S. Armini,
Robert O'Connor,
Anita Brday-Boyd