Journal Article


J. M. Don MacElroy
Denis P. Dowling
Mahfujur Rahman
Damian A. Mooney
Michael T P McCann



layers titania pore size grain boundaries magnetron sputtering columnar structure grain structure silica

Novel, nanoporous silica and titania layers fabricated by magnetron sputtering. (2011)

Abstract Composite asymmetric membranes are fabricated through the deposition of submicrometer thick (100 nm) silica (SiO(2)) and titania (TiO(2)) films onto flat nanoporous silica and zirconia substrates by magnetron sputtering. The deposition conditions for both coating types were systematically altered to determine their influence on the deposited coating morphology and thickness. Ideal He/N(2) gas selectivity was measured for all of the membranes. The TiO(2) coatings, when deposited onto a ZrO(2) support layer with a pore size of 3 nm, formed a long columnar grain structure with average column diameter of 38 nm. A similar columnar structure was observed for TiO(2) coatings deposited onto a SiO(2) support layer with a pore size of 1 nm. Under the same conditions, SiO(2) coatings, deposited onto the same SiO(2) supports, formed a closely packed spherical grain structure whereas, when deposited onto ZrO(2) supports, the SiO(2) coatings formed an open grain structure. The average SiO(2) grain diameter was 36 nm in both cases. This preliminary investigation was aimed at studying the effect of sputtering parameters on the density and morphology of the deposited coatings. For the depositions carried out, the coating material was found to be very dense. However, the presence of grain boundaries resulted in poor ideal He/N(2) separation efficiencies.
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Full list of authors on original publication

J. M. Don MacElroy, Denis P. Dowling, Mahfujur Rahman, Damian A. Mooney, Michael T P McCann

Experts in our system

J. M. Don MacElroy
University College Dublin
Total Publications: 46
Denis P. Dowling
University College Dublin
Total Publications: 50