Type

Conference Proceedings

Authors

Simon B. Newcomb
M. Serantoni
David Sutton
V. J. Cunnane
D. Noel Buckley
E. Harvey
T. Melly
Colm O'Dwyer

Subjects

Physics

Topics
porous inp layers spectroscopic ellipsometry transmission electron microscopy thin film anodization koh electrolytes thick films porous oxide films

Anodic oxidation of InP in KOH electrolytes (2002)

Abstract The anodic behavior of InP in 1 mol dm-3 KOH was investigated and compared with its behavior at higher concentrations of KOH. At concentrations of 2 mol dm-3 KOH or greater, selective etching of InP occurs leading to thick porous InP layers near the surface of the sustrate. In contrast, in 1 mol dm-3 KOH, no such porous layers are formed but a thin surface film is formed at potentials in the range 0.6 V to 1.3 V. The thickness of this film was determined by spectroscopic ellipsometry as a function of the upper potential and the measured film thickness corresponds to the charge passed up to a potential of 1.0 V. Anodization to potentials above 1.5 V in 1 mol dm- 3 KOH results in the growth of thick, porous oxide films (~ 1.2 ┬Ám). These films are observed to crack, ex-situ, due to shrinkage after drying in ambient air. Comparisons between the charge density and film thickness measurements indicate a porosity of approximately 77% for such films.
Collections Ireland -> University College Cork -> College of Science, Engineering and Food Science
Ireland -> University College Cork -> Chemistry - Conference Items
Ireland -> University College Cork -> Chemistry

Full list of authors on original publication

Simon B. Newcomb, M. Serantoni, David Sutton, V. J. Cunnane, D. Noel Buckley, E. Harvey, T. Melly, Colm O'Dwyer

Experts in our system

1
D. Noel Buckley
University College Cork
Total Publications: 27
 
2
Colm O'Dwyer
University College Cork
Total Publications: 121