Type

Journal Article

Authors

M.P Brandon
Ian J Godwin
Richard L Doyle
Michael Edward Lyons

Subjects

Chemistry

Topics
electrochemical electrodes electrochemical properties modified electrodes electrocatalysis iron and nickel oxide redox properties oxygen evolution kinetics mechanism electrochemical water splitting

Redox and electrochemical water splitting catalytic properties of hydrated metal oxide modified electrodes (2013)

Abstract This paper presents a review of the redox and electrocatalytic properties of transition metal oxide electrodes, paying particular attention to the oxygen evolution reaction. Metal oxide materials may be prepared using a variety of methods, resulting in a diverse range of redox and electrocatalytic properties. Here we describe the most common synthetic routes and the important factors relevant to their preparation. The redox and electrocatalytic properties of the resulting oxide layers are ascribed to the presence of extended networks of hydrated surface bound oxymetal complexes termed surfaquo groups. This interpretation presents a possible unifying concept in water oxidation catalysis ? bridging the fields of heterogeneous electrocatalysis and homogeneous molecular catalysis.
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Full list of authors on original publication

M.P Brandon, Ian J Godwin, Richard L Doyle, Michael Edward Lyons

Experts in our system

1
Michael Brandon
University of Limerick
Total Publications: 5
 
2
Ian Godwin
Trinity College Dublin
Total Publications: 10
 
3
Michael Lyons
Trinity College Dublin
Total Publications: 41